高压烧结法制备Bi2Te3纳米晶块体热电性能的研究?
Thermoelectric properties of the Bi2Te3 nanocrystalline bulk alloy pressed by the high-pressure sintering
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摘要: 用高压烧结法对水热法制备的Bi2 Te3纳米线及纳米颗粒粉体进行了压制成型,并与真空热压法制备的样品进行了形貌和热电性能的比较.研究表明,高压烧结样品内的晶粒尺寸明显小于热压样品.热电性能的研究表明,高压烧结样品的电阻率、赛贝克系数和热导率均优于真空热压样品.由纳米线粉体高压烧结的样品其热电优值Z T在室温时达到了0.5,高于真空热压样品的值,表明高压烧结是热电材料纳米粉体成型的一种有效方法.Abstract: Bi2Te3 nanowires and nanoparticles are synthesized by hydrothermal method, and the nanopowders are pressed into bulk pellets by high-pressure sintering or vacuum hot-pressed. The scanning electron microscope (SEM) results and thermal properties of such bulk samples are compared. The SEM result shows that the grain size of the high-pressure sintering sample is much smaller than that of the hot-pressed sample. The thermal properties show that the electrical resistivity, Seebeck coe?cient, and thermal conductivity of the high-pressure sintering sample are all better than those of the hot-pressed sample. The ZT value of the high-pressure sintering sample prepared by nanowires reaches 0.5 at room temperature, which is much higher than that of the hot-pressed sample. Therefore the high-pressure sintering provides an effective method to press nanopowders to bulk.
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