PrNi2的磁和磁热性能研究
Investigation on the magnetic and magneto caloric prop erties of PrNi2
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摘要: 在一些磁性材料内,磁性离子间交换作用和磁性离子的自旋涨落对材料磁性有影响.本文根据磁比热实验值确定了晶场参数后,利用包含自旋涨落的交换作用有效场Hm = n0(1+γT +βeωT )M ,计算了PrNi2晶体晶场能级的Zeeman劈裂.在温度为3.8 K 6 T 630 K范围内,计算了该晶体多晶磁矩随外磁场的变化,以及外磁场H =5000 Oe时磁化率倒数随温度的变化,计算结果和实验值符合较好.当外磁场在0-50000 Oe时,计算的该晶体的磁熵变与已有文献的理论结果相似.计算结果说明,提出的包含自旋涨落的交换作用有效场不仅适合亚铁磁性晶体,而且也适合顺磁性晶体.Abstract: The magnetic properties of some magnetic materials are influenced by the exchange interaction between magnetic ions and the spin fluctuations of magnetic ions. By use of the exchange interaction-effective field including the spin fluctuations of magnetic ions Hm=n0(1+γT+βeωT )M, the Zeeman splitting of crystal field energy levels of Pr3+ ions in PrNi2 and the variation of the magnetic moments with the applied field in a temperature range of 3.8 K 6 T 6 30 K are calculated. The thermal variation of the reciprocal susceptibility of Pr3+ ions is calculated as well for the applied magnetic field H =5000 Oe. The calculated results are in good agreement with the experimental data. The magnetic entropy changes are obtained theoretically in a magnetic field range of 0
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