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2007 Volume 24 Issue 4
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SUN Guang, LIU Zhong-Yuan, HE Ju-Long, Yu Dong-Li, TIAN Yong-Jun. 2007: Chemical Synthesis of C3N and BC2N Compounds, Chinese Physics Letters, 24(4): 1092-1094.
Citation: SUN Guang, LIU Zhong-Yuan, HE Ju-Long, Yu Dong-Li, TIAN Yong-Jun. 2007: Chemical Synthesis of C3N and BC2N Compounds, Chinese Physics Letters, 24(4): 1092-1094.
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Chemical Synthesis of C3N and BC2N Compounds

  • State Key Laboratory of Metastable Materials Science and Technology,Yanshan University,Qinhuangdao 066004

  • Available Online: 30/04/2007
  • Fund Project: the National Natural Science Foundation of China under Grant Nos 50225207,10325417,50372055,50472051and 50532020,and the National Basic Research Programme of China under Grant No 2005CB724400
  • A chemical reaction for the preparation of B-C-N compounds by using carbon tetrachloride(CCl4),boron tribromide(BBr3),lithium nitride(Li3N) and sodium as reactants has been carried out at the temperature of 400°C.Measurements of FTIR,XRD,TEM and EELS show that two kinds of compounds have been formed in the prepared sample.One is hollow sphere-like C-N with an amorphous.structure;the other is piece-like polycrystalline B-C-N with the hexagonal structure.Their determined compositions are close to C3N and BC2N,respectively.
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    沈阳化工大学材料科学与工程学院 沈阳 110142

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Chemical Synthesis of C3N and BC2N Compounds

  • Available Online: 30/04/2007

Abstract: A chemical reaction for the preparation of B-C-N compounds by using carbon tetrachloride(CCl4),boron tribromide(BBr3),lithium nitride(Li3N) and sodium as reactants has been carried out at the temperature of 400°C.Measurements of FTIR,XRD,TEM and EELS show that two kinds of compounds have been formed in the prepared sample.One is hollow sphere-like C-N with an amorphous.structure;the other is piece-like polycrystalline B-C-N with the hexagonal structure.Their determined compositions are close to C3N and BC2N,respectively.

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