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2008 Volume 17 Issue 3
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Zhu Rong-Jiao, Xu Wei, Tian Yi-Ling, Hao Ji-Shuang. 2008: Fusion curves and thermodynamic properties of carbon tetrachloride, chloroform, bromoform and silicon tetrachloride at pressure up to 3500 Mpa, Chinese Physics B, 17(3): 1088-1093.
Citation: Zhu Rong-Jiao, Xu Wei, Tian Yi-Ling, Hao Ji-Shuang. 2008: Fusion curves and thermodynamic properties of carbon tetrachloride, chloroform, bromoform and silicon tetrachloride at pressure up to 3500 Mpa, Chinese Physics B, 17(3): 1088-1093.
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Fusion curves and thermodynamic properties of carbon tetrachloride, chloroform, bromoform and silicon tetrachloride at pressure up to 3500 Mpa

  • Department of Chemistry, Institute of Science, Tianjin University, Tianjin 300072, China

  • Available Online: 30/03/2008
  • Fund Project: the National Natural Science Foundation of China (Grant 20476071)
  • The fusion temperature as a function of pressure for carbon tetrachloride, chloroform, bromoform and silicon tetrachloride at pressures up to 3500MPa has been determined. The experimental data were fitted by the equation Tfus = T0(1 + Ap/a1)a2 exp(-a3△p) and the changes of the molar enthalpy and molar internal energy on fusion were calculated using the parameters of the fitted equation. Comparisons with the data from the literature show that the experimental data, parameters of fitted equations, changes of the molar enthalpy and molar internal energy are reliable.
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Fusion curves and thermodynamic properties of carbon tetrachloride, chloroform, bromoform and silicon tetrachloride at pressure up to 3500 Mpa

  • Available Online: 30/03/2008

Abstract: The fusion temperature as a function of pressure for carbon tetrachloride, chloroform, bromoform and silicon tetrachloride at pressures up to 3500MPa has been determined. The experimental data were fitted by the equation Tfus = T0(1 + Ap/a1)a2 exp(-a3△p) and the changes of the molar enthalpy and molar internal energy on fusion were calculated using the parameters of the fitted equation. Comparisons with the data from the literature show that the experimental data, parameters of fitted equations, changes of the molar enthalpy and molar internal energy are reliable.

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